PHOTOOXIDATION OF CYCLOHEXANE BY (BU4N)2CR4O13 IN ACETONITRILE OR CH2CL2

被引：2
|
作者：
SHULPIN, GB
DRUZHININA, AN
NIZOVA, GV
机构：
[1] N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
来源：
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1990年 / 39卷 / 01期
关键词：
D O I：
10.1007/BF00963032
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Upon irradiation using light with λ >520 nm, (Bu4N)2Cr4O13 oxidizes cyclohexane to cyclohexanol as the major product and cyclohexanone in acetonitrile and to cyclohexanol as the major product, cyclohexanone, and cyclohexyl chloride in CH2Cl2. Carrying out this reaction in the presence of air leads to a sharp increase in the yield of cyclohexanone. © 1990 Plenum Publishing Corporation.
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页码：195 / 196
页数：2
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