CONTRIBUTION OF ANHARMONIC VIBRATIONS OF STRUCTURAL ELEMENTS TO THE FORMATION OF THERMOPHYSICAL PROPERTIES OF LINEAR POLYMERS

被引:2
作者
Kolupaev, B. B. [1 ]
机构
[1] Rovno State Humanities Univ, 31 Ostafov Str, UA-33023 Rovno, Ukraine
关键词
jet element; anharmonicity; linear polymers; macromolecule;
D O I
10.1007/s10891-011-0613-6
中图分类号
O414.1 [热力学];
学科分类号
摘要
The contribution of the higher terms of expansion of the Lennard-Jones interaction potential between structural elements of linear polymers to the value of heat capacity and thermal conductivity of the material has been determined. The established interrelationship of the microcharacteristics and macroproperties of the systems makes it possible to use the procedure of calculation of Cp and. in production and operation of polymer materials.
引用
收藏
页码:1421 / 1428
页数:8
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