CONCENTRATION STEP DETERMINATION OF DIFFUSION AND PARTITION-COEFFICIENTS OF FERROCYANIDE FOR MEMBRANE-COATED ROTATING-DISK ELECTRODE

被引：4

作者：

MIYAWAKI, O ^{[1
]}

WINGARD, LB ^{[1
]}

机构：

[1] UNIV PITTSBURGH,SCH MED,DEPT PHARMACOL,PITTSBURGH,PA 15261

来源：

BIOTECHNOLOGY AND BIOENGINEERING | 1988年 / 31卷 / 02期

关键词：

BIOTECHNOLOGY - ENZYMES - Immobilization - MATHEMATICAL MODELS - Industrial Applications;

D O I：

10.1002/bit.260310212

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

In this article the diffusion coefficient D//m and the partition coefficient alpha for potassium ferrocyanide in a bovine serum albumin membrane were measured using the steady-state method and the concentration step transient method. This material was selected for the membrane since cross-linked albumin is frequently used as a support for the immobilization of enzymes. As the diffusion resistance of the membrane was far greater than that of the solution boundary layer, the mass transfer resistance of the Levich boundary layer could be neglected.

引用

页码：179 / 182

页数：4

共 18 条

[1] DETERMINATION OF THE CONCENTRATION-DEPENDENCE OF ELECTROLYTE DIFFUSION-COEFFICIENTS WITH THE ROTATING-DISK ELECTRODE
ENGELGARDT, GR
DAVYDOV, AD
KRYLOV, VS
SOVIET ELECTROCHEMISTRY, 1987, 23 (01): : 132 - 133
[2] CALCULATION OF DIFFUSION-COEFFICIENTS FROM ROTATING-DISK ELECTRODE DATA
BRUCKENSTEIN, S
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1975, 122 (09) : 1215 - 1215
[3] SIMULTANEOUS ELECTROCHEMICAL DETERMINATION OF DIFFUSION AND PARTITION-COEFFICIENTS OF POTASSIUM FERROCYANIDE FOR ALBUMIN GLUTARALDEHYDE MEMBRANES
MARRESE, CA
MIYAWAKI, O
WINGARD, LB
ANALYTICAL CHEMISTRY, 1987, 59 (02) : 248 - 252
[4] GENERAL DETERMINATION OF CONCENTRATION IMPEDANCE (CONVECTIVE DIFFUSION AND CHEMICAL-REACTION) FOR ROTATING-DISK ELECTRODE
LEVART, E
SCHUHMAN.D
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1974, 53 (01): : 77 - 94
[5] DETERMINATION OF MOLECULAR-DIFFUSION COEFFICIENTS IN SATURATED SOLUTIONS BY ROTATING-DISK METHOD
KISHINEVSKII, MK
KORNIENKO, TS
STEPYGIN, VI
ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (05): : 1250 - 1252
[6] TRANSIENT MASS-TRANSFER AT A COATED ROTATING-DISK ELECTRODE - DIFFUSION AND ELECTROHYDRODYNAMIC IMPEDANCES
DESLOUIS, C
TRIBOLLET, B
DUPRAT, M
MORAN, F
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (10) : 2496 - 2501
[7] DETERMINATION OF DIFFUSION-COEFFICIENTS OF ANIONS AT A ROTATING SILVER DISK ELECTRODE
SHIMIZU, K
OSTERYOUNG, RA
ANALYTICAL CHEMISTRY, 1981, 53 (14) : 2350 - 2351
[8] THEORY OF THE ROTATING-DISK METHOD IN BINARY ELECTROLYTES AT CONCENTRATION DEPENDENT COEFFICIENTS OF DIFFUSION AND CONCENTRATION DEPENDENT VISCOSITY
KUBICEK, P
CHEMICKE ZVESTI, 1979, 33 (01): : 23 - 51
[9] IMPROVEMENTS IN ROTATION RATE STEP EXPERIMENTS TO EVALUATE DIFFUSION-COEFFICIENTS AT ROTATING-DISK ELECTRODES
BLAUCH, DN
ANSON, FC
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 259 (1-2): : 1 - 19
[10] ROTATING-DISK DETERMINATION OF THE DIFFUSION-COEFFICIENTS OF COBALT(II) HYDROXO COMPLEXES IN KOH SOLUTIONS
STEPANOV, AN
KAZARINOV, IA
FETISOVA, TA
SOVIET ELECTROCHEMISTRY, 1986, 22 (05): : 636 - 638

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