PROSPECTS FOR CERAMIC ELECTROCHEMICAL REACTORS IN INDUSTRY

被引：83
作者：
MAZANEC, TJ
机构：
[1] Warrensville Research Cent, Cleveland, United States
来源：
SOLID STATE IONICS | 1994年 / 70卷 / pt 1期
关键词：
D O I：
10.1016/0167-2738(94)90282-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Ceramic electrochemical reactors are being investigated to cogenerate electricity and chemicals in revolutionary new processes. Advantages of the new electroceramic processes are envisioned to include enhanced catalytic activity and selectivity due to electrocatalysis trocatalysis, better process integration, reduced feedstock costs, and uniquely active surfaces for chemical reaction (NEMCA). Prospects for realizing these advantages are evaluated in the context of industrial requirements. Revision of the conventional equation of oxygen flux is suggested and new correlations among membrane properties are presented.
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页码：11 / 19
页数：9
相关论文
共 49 条
[1]   CATALYSIS WITH PERMSELECTIVE INORGANIC MEMBRANES [J].
ARMOR, JN .
APPLIED CATALYSIS, 1989, 49 (01) :1-25
[2]   SURFACE OXYGEN-EXCHANGE PROPERTIES OF BISMUTH OXIDE-BASED SOLID ELECTROLYTES AND ELECTRODE MATERIALS [J].
BOUKAMP, BA ;
VINKE, IC ;
DEVRIES, KJ ;
BURGGRAAF, AJ .
SOLID STATE IONICS, 1989, 32-3 :918-923
[3]   OXYGEN SEMIPERMEABILITY OF ERBIA-STABILIZED BISMUTH OXIDE [J].
BOUWMEESTER, HJM ;
KRUIDHOF, H ;
BURGGRAAF, AJ ;
GELLINGS, PJ .
SOLID STATE IONICS, 1992, 53 :460-468
[4]  
CALBE TL, 1990, Patent No. 399833
[5]   OXIDATION AND AMMOXIDATION OF PROPYLENE OVER BISMUTH MOLYBDATE CATALYST [J].
CALLAHAN, JL ;
GRASSELLI, RK ;
MILBERGER, EC ;
STRECKER, HA .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1970, 9 (02) :134-+
[6]   OXYGEN-TRANSPORT IN SELECTED NONSTOICHIOMETRIC PEROVSKITE-STRUCTURE OXIDES [J].
CARTER, S ;
SELCUK, A ;
CHATER, RJ ;
KAJDA, J ;
KILNER, JA ;
STEELE, BCH .
SOLID STATE IONICS, 1992, 53 :597-605
[7]   COMPUTATIONAL STUDIES OF SOLID OXIDATION CATALYSTS [J].
CATLOW, CRA ;
JACKSON, RA ;
THOMAS, JM .
JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (20) :7889-7893
[8]  
CLAYSON DM, 1987, Patent No. 2190379
[9]   ON THE SYSTEMATIC SELECTION OF PEROVSKITE SOLID ELECTROLYTES FOR INTERMEDIATE TEMPERATURE FUEL-CELLS [J].
COOK, RL ;
SAMMELLS, AF .
SOLID STATE IONICS, 1991, 45 (3-4) :311-321
[10]   OXIDATIVE DEHYDRODIMERIZATION OF PROPYLENE OVER A BI2O3 - LA2O3 OXIDE ION-CONDUCTIVE CATALYST [J].
DICOSIMO, R ;
BURRINGTON, JD ;
GRASSELLI, RK .
JOURNAL OF CATALYSIS, 1986, 102 (01) :234-239
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