A STUDY OF PARA-TOLUENESULPHONATE ANION ADSORPTION AT THE GOLD (311) SINGLE-CRYSTAL ELECTRODE

被引:8
|
作者
SKOLUDA, P
DUTKIEWICZ, E
机构
来源
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 329卷 / 1-2期
关键词
D O I
10.1016/0022-0728(92)80222-P
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The adsorption of p-toluenesulphonate anions at the gold (311) single crystal electrode has been investigated by cyclic voltammetry and differential capacity measurements. The results have been fitted with the Frumkin isotherm. The adsorption parameters such as the surface coverage, the standard Gibbs energy of adsorption and the electrosorption valencies have been determined. The present data are compared with those obtained at polycrystalline gold.
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页码:279 / 287
页数:9
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