ON THE ELECTROCHEMICAL FLUORINATION OF DERIVATIVES OF MORPHOLINE AND PIPERIDINE

被引：17
|
作者：
MEINERT, H
FACKLER, R
MADER, J
REUTER, P
ROHLKE, W
机构：
[1] Universität Ulm, 7900 Ulm
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 01期
关键词：
D O I：
10.1016/S0022-1139(00)80306-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.
引用
收藏
页码：53 / 73
页数：21
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