ON THE ELECTROCHEMICAL FLUORINATION OF DERIVATIVES OF MORPHOLINE AND PIPERIDINE

被引：17
|
作者：
MEINERT, H
FACKLER, R
MADER, J
REUTER, P
ROHLKE, W
机构：
[1] Universität Ulm, 7900 Ulm
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 51卷 / 01期
关键词：
D O I：
10.1016/S0022-1139(00)80306-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.
引用
收藏
页码：53 / 73
页数：21
相关论文
共 50 条
  • [1] THE ELECTROCHEMICAL FLUORINATION OF DERIVATIVES OF MORPHOLINE, PIPERIDINE AND CARBAZOLE
    MEINERT, H
    FACKLER, R
    MADER, J
    REUTER, P
    ROHLKE, W
    JOURNAL OF FLUORINE CHEMISTRY, 1992, 59 (03) : 351 - 365
  • [2] Morpholine, Piperazine, and Piperidine Derivatives as Antidiabetic Agents
    Zolotareva, Darya
    Zazybin, Alexey
    Dauletbakov, Anuar
    Belyankova, Yelizaveta
    Parache, Beatriz Giner
    Tursynbek, Saniya
    Seilkhanov, Tulegen
    Kairullinova, Anel
    MOLECULES, 2024, 29 (13):
  • [3] REACTION OF BENZYLIDENEACETOPHENONE WITH MORPHOLINE AND PIPERIDINE
    CHIACCHIO, U
    CORSARO, A
    PURRELLO, G
    CHIMICA & L INDUSTRIA, 1979, 61 (02): : 154 - 154
  • [4] ADDITION OF PIPERIDINE AND MORPHOLINE TO CHALCONES
    KOZLOV, NS
    KOZLOV, GN
    JOURNAL OF GENERAL CHEMISTRY USSR, 1963, 33 (07): : 2130 - &
  • [5] Structures of piperazine, piperidine and morpholine
    Parkin, A
    Oswald, IDH
    Parsons, S
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2004, 60 : 219 - 227
  • [6] THE CONFORMATIONS OF PIPERIDINE, MORPHOLINE, AND TRIETHYLAMINE
    ARONEY, M
    LEFEVRE, RJW
    PROCEEDINGS OF THE CHEMICAL SOCIETY OF LONDON, 1958, (03): : 82 - 82
  • [7] POLYCHLOROBENZENESULFENAMIDES ON BASIS OF MORPHOLINE PIPERIDINE AND CYCLOHEXYLAMINE
    EITINGON, II
    STRELNIK.NP
    JOURNAL OF GENERAL CHEMISTRY USSR, 1964, 34 (05): : 1617 - &
  • [8] Synthesis of fluorinated triazole and isoxazole derivatives by electrochemical fluorination
    Kuribayashi, Shunsuke
    Shida, Naoki
    Inagi, Shinsuke
    Fuchigami, Toshio
    TETRAHEDRON, 2016, 72 (35) : 5343 - 5349
  • [9] ELECTROCHEMICAL FLUORINATION OF ANTHRACENE-DERIVATIVES .2.
    CARPENTER, JF
    EKES, LH
    KING, PF
    MARIANI, HA
    ZADEH, MM
    OMALLEY, RF
    ROMAN, VJ
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1983, 130 (11) : 2170 - 2172
  • [10] Synthesis, identification, and benzene solubility of the piperidine, pyrrolidine, and morpholine derivatives of fullerene C60
    K. N. Semenov
    N. A. Charykov
    V. A. Keskinov
    Russian Journal of Physical Chemistry A, 2013, 87 : 54 - 57
12345