DIRECT OBSERVATION OF 2ND EXCITED 1,3(N,PI-STAR) STATES OF PYRAZINE BY UV-IR DOUBLE-RESONANCE DIP SPECTROSCOPY

被引：42
作者：
OKUZAWA, Y
FUJII, M
ITO, M
机构：
[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 04期
关键词：
D O I：
10.1016/0009-2614(90)85374-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
UV-IR fluorescence and phosphorescence dip spectroscopy have been applied for the observation of the second excited 1,3(n,π*) states pyrazine in the vapor. The observed state energies agree very well with those of the ab initio calculation with DZCI. © 1990.
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页码：341 / 346
页数：6
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共 35 条
[11]   CONFIGURATION INTERACTION STUDIES OF GROUND AND EXCITED STATES OF POLYATOMIC MOLECULES .2. ELECTRONIC STATES AND SPECTRUM OF PYRAZINE [J].
HACKMEYER, M ;
WHITTEN, JL .
JOURNAL OF CHEMICAL PHYSICS, 1971, 54 (09) :3739-+
[12]   INTERACTION OF ORBITALS THROUGH SPACE AND THROUGH BONDS [J].
HOFFMANN, R .
ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (01) :1-&
[13]   BENZYNES DEHYDROCONJUGATED MOLECULES AND INTERACTION OF ORBITALS SEPARATED BY A NUMBER OF INTERVENING SIGMA BONDS [J].
HOFFMANN, R ;
IMAMURA, A ;
HEHRE, WJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (06) :1499-&
[14]   LOWEST SINGLET AND TRIPLET EXCITED-STATES OF PYRAZINE [J].
HONG, HK ;
ROBINSON, GW .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1974, 52 (01) :1-20
[15]   ELECTRONIC STATES OF AZABENZENES - A CRITICAL REVIEW [J].
INNES, KK ;
BYRNE, JP ;
ROSS, IG .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1967, 22 (02) :125-&
[16]   FORBIDDEN CHARACTER IN 3200-A TRANSITIONS OF PYRAZINE-H4 AND -D4 VAPORS [J].
INNES, KK ;
TILFORD, SG ;
SIMMONS, JD .
JOURNAL OF MOLECULAR SPECTROSCOPY, 1963, 11 (04) :257-&
[17]   ULTRA-VIOLET ABSORPTION SPECTRA OF THE DIAZINES [J].
INNES, KK ;
MERRITT, JA ;
TINCHER, WC ;
TILFORD, SG .
NATURE, 1960, 187 (4736) :500-501
[18]   TRIPLET-TRIPLET ABSORPTION OF PYRAZINE RELATED TO THE N+PI-STAR(B3U)-N-PI-STAR(B2G) SPLITTING [J].
INOUE, A ;
WEBSTER, D ;
LIM, EC .
JOURNAL OF CHEMICAL PHYSICS, 1980, 72 (02) :1419-1420
[19]   ULTRAVIOLET ABSORPTION OF PYRAZINE VAPOR DUE TO N-PL-TRANSITION [J].
ITO, M ;
SHIMADA, R ;
KURAISHI, T ;
MIZUSHIMA, W .
JOURNAL OF CHEMICAL PHYSICS, 1957, 26 (06) :1508-1515
[20]   RADIATIONLESS DECAY IN AZABENZENES AS STUDIED BY OPTO-ACOUSTIC SPECTROSCOPY [J].
KAYA, K ;
CHATELAIN, CL ;
ROBIN, MB ;
KUEBLER, NA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (08) :2153-2161
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