SINGLE ELECTRON-TRANSFER AS RATE-DETERMINING STEP IN AN ALIPHATIC NUCLEOPHILIC-SUBSTITUTION

被引：121
|
作者：
LUND, T [1 ]
LUND, H [1 ]
机构：
[1] AARHUS UNIV,DEPT ORGAN CHEM,DK-8000 AARHUS C,DENMARK
来源：
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY | 1986年 / 40卷 / 06期
关键词：
D O I：
10.3891/acta.chem.scand.40b-0470
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
引用
收藏
页码：470 / 485
页数：16
相关论文
共 50 条
  • [31] Spectral evidence for single electron transfer in nucleophilic aliphatic substitution of a carbanion by methyl iodide.
    Tolbert, LM
    Bedlek, J
    Terapane, M
    Kowalik, J
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 248 - ORGN
  • [32] The Rate-Determining Step is Dead. Long Live the Rate-Determining State!
    Kozuch, Sebastian
    Martin, Jan M. L.
    CHEMPHYSCHEM, 2011, 12 (08) : 1413 - 1418
  • [33] Multielectron oxidation of anthracenes with a one-electron oxidant via water-accelerated electron-transfer disproportionation of the radical cations as the rate-determining step
    Fukuzumi, S
    Nakanishi, I
    Tanaka, K
    JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (50) : 11212 - 11220
  • [34] PHOTO-SMILES REARRANGEMENT .4. ELECTRON-TRANSFER MECHANISM OF AN INTRA-MOLECULAR AROMATIC NUCLEOPHILIC-SUBSTITUTION
    NAKAGAKI, R
    HIRAMATSU, M
    MUTAI, K
    NAGAKURA, S
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 126 (01): : 69 - 75
  • [35] ELECTRON-TRANSFER VERSUS NUCLEOPHILIC-SUBSTITUTION IN THE REACTIONS OF ALPHA-HALOGENATED 4-NITROTOLUENES WITH BASE .1.
    KAM, TS
    LIM, TM
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (02): : 147 - 150
  • [36] 3-ELECTRON NUCLEOPHILIC-SUBSTITUTION REACTIONS
    DINNOCENZO, JP
    TODD, WP
    SIMPSON, TR
    LIEBERMAN, DR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 185 - ORGN
  • [37] VARIATION IN THE TRANSITION-STATE STRUCTURE OF ALIPHATIC NUCLEOPHILIC-SUBSTITUTION
    ANDO, T
    KIMURA, T
    YAMATAKA, H
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 190 (SEP): : 172 - ORN
  • [38] ABOUT THE RADICAL MECHANISM OF THE OXIDATIVE COUPLING OF THE DIANIONS OF CARBOXYLIC-ACIDS - COMPETITION BETWEEN NUCLEOPHILIC-SUBSTITUTION AND ELECTRON-TRANSFER
    AURELL, MJ
    GIL, S
    MESTRES, R
    PARRA, M
    TORTAJADA, A
    ANALES DE QUIMICA, 1994, 90 (7-8): : 457 - 466
  • [39] VARIATION IN THE TRANSITION-STATE STRUCTURE OF ALIPHATIC NUCLEOPHILIC-SUBSTITUTION
    ANDO, T
    KIMURA, T
    YAMATAKA, H
    ADVANCES IN CHEMISTRY SERIES, 1987, (215): : 103 - 114
  • [40] RATE-DETERMINING PROTON TRANSFER IN SUBSTITUTION ON TETRAHEDRAL HYDROGEN CHROMATE(VI)
    LIN, CT
    BEATTIE, JK
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1971, (NSEP): : 100 - &
12345