STUDY OF (TETRAPHENYLPORPHINATO)MANGANESE(III)-CATALYZED EPOXIDATION AND DEMETHYLATION USING PARA-CYANO-N,N-DIMETHYLANILINE N-OXIDE AS OXYGEN DONOR IN A HOMOGENEOUS SYSTEM - KINETICS, RADIOCHEMICAL LIGATION STUDIES, AND REACTION-MECHANISM FOR A MODEL OF CYTOCHROME-P-450

被引:137
作者
POWELL, MF [1 ]
PAI, EF [1 ]
BRUICE, TC [1 ]
机构
[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106
关键词
D O I
10.1021/ja00323a036
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:3277 / 3285
页数:9
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[1]   ON PREPARATION OF METALLOPORPHYRINS [J].
ADLER, AD ;
LONGO, FR ;
KAMPAS, F ;
KIM, J .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&
[2]   SYNTHESIS OF CAPPED PORPHYRINS [J].
ALMOG, J ;
BALDWIN, JE ;
CROSSLEY, MJ ;
DEBERNARDIS, JF ;
DYER, RL ;
HUFF, JR ;
PETERS, MK .
TETRAHEDRON, 1981, 37 (21) :3589-3601
[3]  
Antonini E., 1971, HEMOGLOBIN MYOGLOBIN
[4]   MANGANESE PORPHYRIN COMPLEXES [J].
BOUCHER, LJ .
COORDINATION CHEMISTRY REVIEWS, 1972, 7 (03) :289-&
[5]   MANGANESE PORPHYRIN COMPLEXES .5. AXIAL INTERACTIONS IN MANGANESE(III) PORPHYRINS [J].
BOUCHER, LJ .
ANNALS OF THE NEW YORK ACADEMY OF SCIENCES, 1973, 206 (OCT22) :409-419
[6]   REACTION OF IRON(III) PORPHYRINS AND IODOSOXYLENE - ACTIVE OXENE COMPLEX OF CYTOCHROME-P-450 [J].
CHANG, CK ;
KUO, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (12) :3413-3415
[7]   NIH SHIFT IN HAEMIN-IODOSYLBENZENE-MEDIATED HYDROXYLATIONS [J].
CHANG, CK ;
EBINA, F .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (15) :778-779
[8]  
COON MJ, 1980, METAL ION ACTIVATION
[9]   SELECTIVE OXIDATION OF 3,5,5-TRIMETHYLCYCLOHEXENE-3 ONE (BETA-ISOPHORONE) TO 3,5,5-TRIMETHYLCYCLOHEXENE-1,4 DIONE BY OXYGEN CATALYZED BY MNII OR COII CHELATES [J].
COSTANTINI, M ;
DROMARD, A ;
JOUFFRET, M ;
BROSSARD, B ;
VARAGNAT, J .
JOURNAL OF MOLECULAR CATALYSIS, 1980, 7 (01) :89-97
[10]   AN IMPROVED PREPARATION OF TERTIARY AMINE N-OXIDES [J].
CRAIG, JC ;
PURUSHOT.KK .
JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (05) :1721-&