UV SPECTROSCOPY AND PHOTOCHEMISTRY OF THE DIBENZOPLATINOL SYSTEM

被引：13

作者：

BRUNE, HA ^{[1
]}

HOHENADEL, R ^{[1
]}

SCHMIDTBERG, G ^{[1
]}

ZIEGLER, U ^{[1
]}

机构：

[1] UNIV ULM,SEKT MASSENSPEKTROMETRIE,W-7900 ULM,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)83062-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dibenzoplatinol system has been irradiated with monochromatic UV-radiation of wavelengths lambda = 253.2, 278.8, 313.7, 348.1 nm and studied with respect to photochemical reactivity. All 15 compounds were completely photo-stable within the cited wavelength interval. The results are discussed with respect to the mechanism of the reductive elimination of the biphenyl system from cis-bis(phenyl)platinum(II) complexes.

引用

页码：179 / 199

页数：21

共 44 条

[1] E,Z-ATROPISOMERISM IN SUBSTITUTED CIS-BIS(PHENYL)PLATINUM(II) COMPOUNDS .2. (1,2,5,6-ETA-4-CYCLOOCTA-1,5-DIENE)BIS(2-METHOXYMETHYL-6-METHYL-PHENYL)PLATINUM(II) [J].