HYDROCARBON BRIDGED METAL-COMPLEXES .28. FISCHER-METAL CARBENE DITHIOLATE ANIONS AS NUCLEOPHILES FOR FORMATION OF HYDROCARBON-BRIDGED METAL-COMPLEXES

被引：10

作者：

WEIDMANN, T ^{[1
]}

SUNKEL, K ^{[1
]}

BECK, W ^{[1
]}

机构：

[1] LUDWIG MAXIMILIANS UNIV MUNCHEN,INST ANORGAN CHEM,MEISERSTR 1,D-80333 MUNICH,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 459卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)86074-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of the in situ generated anion (OC)5W=C(NEt2)CH2CS2- to the organometallic Lewis acid, (OC)5Re+ and Ph3PAu+ gives the ligand-bridged complexes (OC)5W=C(NEt2)CH2C(S)S-Re(CO)5 (1) and (OC)5W=C(NEt2)CH2C(S)-S-AuPPh3 (2), respectively. The dianion (OC)5W=C(NEt2)CH=CS22- affords with MeI, Cl2M(PPh3)2 (M = Pd, Pt) and (OC)5Re+ the complexes (OC)4W=C(NEt2)CH=C(SMe)SMe (3), (OC)5W=C(NEt2)CH=CS2M(PR3)2 (4,5) and (OC)5W=C(NEt2)CH=CS2 (Re(CO)5]2 (6). The anion (OC)5W=C(NEt2)CH2CS2- is added to coordinated ethene and allyl ligands of cationic complexes with formation of the hydrocarbon-bridged ComPounds (OC)5W=C(NEt2)CH2C(S)SCH2CH2-W(CO)3CP (7), (OC)5W=C(NEt2)-CH2C(S)SCH2CH2-Re(CO)5 (8) and (OC)5W=C(NEt2)CH2C(S)SCH2CH=CH2-eta2-Mo(NO)(CO)Cp (9), respectively. The structure of 6 has been determined by X-ray diffraction.

引用

页码：219 / 227

页数：9

共 50 条

[21] BRIDGED PHTHALOCYANINATO METAL-COMPLEXES - A NEW CLASS OF INTRINSIC SEMICONDUCTORS
HANACK, M
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 18 - CHED
[22] CHEMICAL AND PHYSICAL-PROPERTIES OF TRIANGULAR BRIDGED METAL-COMPLEXES
CANNON, RD
WHITE, RP
PROGRESS IN INORGANIC CHEMISTRY, 1988, 36 : 195 - 298
[23] BRIDGED PHTHALOCYANINATO METAL-COMPLEXES - A NEW CLASS OF INTRINSIC SEMICONDUCTORS
HANACK, M
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 34 - POLY
[24] TETRAZINE-BRIDGED PHTHALOCYANINATO METAL-COMPLEXES AS SEMICONDUCTING MATERIAL
HANACK, M
LANGE, A
GROSSHANS, R
SYNTHETIC METALS, 1991, 45 (01) : 59 - 70
[25] SYNTHESIS OF CARBYNE METAL-COMPLEXES CONTAINING UNSATURATED HYDROCARBON LIGANDS
MAYR, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 56 - INOR
[26] LIGANDS AND THE FORMATION OF METAL-COMPLEXES
GARNOVSKII, AD
KOORDINATSIONNAYA KHIMIYA, 1988, 14 (05): : 579 - 599
[27] REACTIONS OF METAL-COMPLEXES CATALYZED BY ELECTROPHILES AND NUCLEOPHILES
BANERJEA, D
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1990, 67 (04) : 286 - 294
[28] LUMINESCENCE LIFETIMES IN HALOGEN BRIDGED MIXED-VALENCE METAL-COMPLEXES
WADA, Y
ERA, K
SOLID STATE COMMUNICATIONS, 1988, 67 (10) : 953 - 956
[29] S-TETRAZINE AS LIGAND FOR MONOMERIC AND BRIDGED MACROCYCLIC METAL-COMPLEXES
KEPPELER, U
DEGER, S
LANGE, A
HANACK, M
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (04): : 344 - 345
[30] Hydrocarbon bridged metal complexes XLV. Dinuclear polyene-bridged Fischer carbene complexes and a star-shaped benzene-bridged tris(ferrocenyl-decapentaenyl) compound
Briel, O
Fehn, A
Beck, W
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 578 (1-2) : 247 - 251

← 1 2 3 4 5 →