CONVENIENT SYNTHESES, BASED ON CYCLOHEXENE OXIDE, OF LIGANDS THAT ARE HIGHLY PREORGANISED FOR METAL-ION SIZE-BASED SELECTIVITY

被引：32

作者：

DESOUSA, AS ^{[1
]}

HANCOCK, RD ^{[1
]}

机构：

[1] UNIV WITWATERSRAND, CTR MOLEC DESIGN, WITWATERSRAND 2050, SOUTH AFRICA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclohexene oxide reacts with strong diastereoselectivity with polyamines to give good yields of well defined. crystalline products where only one, or sometimes two, pendant groups are present, such as N-(2-hydroxycyclohexyl)cyclen or DL-1,7-bis(2-hydroxycyclohexyl)-1,4,7-triazaheptane, which as ligands show strong and predictable preferences for smaller metal ions.

引用

页码：415 / 416

页数：2

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