1,3-DITUNGSTACYCLOBUTADIENES .1. REACTIONS WITH ALKYNES - ALKYNE ADDUCTS AND 1,3-DIMETALLAALLYL DERIVATIVES

被引：48

作者：

CHISHOLM, MH ^{[1
]}

HUFFMAN, JC ^{[1
]}

HEPPERT, JA ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1985年 / 107卷 / 18期

关键词：

D O I：

10.1021/ja00304a017

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5116 / 5136

页数：21

共 40 条

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[6] CHEMISTRY OF DI-METAL AND TRI-METAL COMPLEXES WITH BRIDGING CARBENE OR CARBYNE LIGANDS .17. REACTIONS OF THE COMPOUNDS [RU3(CO)12], [OS3(MU-H)2(MU-CH2)(CO)10], AND [OS3(CO)10(CYCLO-C8H14)2] WITH [W(=CC6H4ME-4)(CO)2(ETA-C5H5)] - CRYSTAL-STRUCTURES OF [OSW2(MU-3-C2(C2(C6H4ME-4)2)(CO)7(ETA-C5H5)2] ( 2 ISOMERS) AND [OS3W(MU-3-CC6H4ME-4)(CO)11(ETA-C5H5)]-C [J].

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[8]

Chisholm M.F., UNPUB

[9] MOLECULAR-STRUCTURE AND DYNAMIC SOLUTION BEHAVIOR OF THE BRIDGING 1,3-DIMETALLAALLYL LIGAND IN (ME3SICH2)4W2(MU-CSIME3)(MU-C3R2SIME3) COMPOUNDS (R=H,ME,PH) FORMED BY INSERTION OF ALKYNES INTO A BRIDGING ALKYLIDYNE LIGAND [J].

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[10] METAL ALKOXIDES - MODELS FOR METAL-OXIDES .4. ALKYNE ADDUCTS OF DITUNGSTEN HEXAALKOXIDES AND EVIDENCE FOR AN EQUILIBRIUM BETWEEN DIMETALLATETRAHEDRANE AND METHYLIDYNEMETAL COMPLEXES - W2(MU-C2H2)REVERSIBLE2W=CH [J].

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