A POTENTIOMETRIC STUDY OF THE COMPLEXATION OF ALIPHATIC ACYCLIC MONOAMINES WITH AG(I) IN 1 M NITRATE

被引：7

作者：

GARNER, R ^{[1
]}

YPERMAN, J ^{[1
]}

MULLENS, J ^{[1
]}

VANPOUCKE, LC ^{[1
]}

机构：

[1] LIMBURGS UNIV CENTRUM,INORGAN & PHYS CHEM LAB,B-3590 DIEPENBEEK,BELGIUM

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 30卷 / 02期

关键词：

ALIPHATIC MONOAMINES; SILVER; COMPLEXES; HYDROLYSIS; MIXED COMPLEXES; STABILITY CONSTANTS;

D O I：

10.1080/00958979308024667

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexation of 12 aliphatic monoamines with Ag(I) has been studied in IM KNO3 at 25-degrees-C using a potentiometric titration technique, performing pH and pAg measurements. To study these ternary systems, the binary systems (Ag-OH, LH, H-OH) were first investigated. The model used for background Ag(I) hydrolysis is consistent with the literature. Graphical techniques were used for the calculation of formation constants of silver-amine complexes. The estimates were further refined using the Superquad program. Evidence has been found for the formation of mixed Ag(I)-hydroxo ligand complexes only with aliphatic primary monoamines.

引用

页码：151 / 164

页数：14

共 40 条

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