TOTAL INTERNAL-REFLECTION FLUORESCENCE MEASUREMENTS OF ION-ASSOCIATION ADSORPTION OF WATER-SOLUBLE PORPHYRINS AT LIQUID-LIQUID INTERFACE

被引:35
|
作者
WATARAI, H [1 ]
SAITOH, Y [1 ]
机构
[1] AKITA UNIV, FAC EDUC, DEPT CHEM, AKITA 010, JAPAN
关键词
D O I
10.1246/cl.1995.283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ion-association adsorption of water-soluble, surface-inactive anionic and cationic porphyrins with the oppositely charged surfactants was observed at toluene/water interface by means of a total internal reflection fluorometry. Water-soluble zinc(II)-porphyrin was also adsorved at the liquid/liquid interface with a hydrophobic zinc(II)-1,10-phenanthroline complex ion.
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页码:283 / 284
页数:2
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