THE ANIONIC 1-AZA-COPE REARRANGEMENT - THEORETICAL EVIDENCE FOR THE INTRAMOLECULAR REACTION OF IMIDE ANIONS WITH ALKENES

被引：6

作者：

WALTERS, MA

机构：

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 39期

关键词：

D O I：

10.1016/0040-4039(95)01482-W

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ab initio calculations at the MP4(SDTQ)/6-31G*//MP2/6-31G* level of theory suggest that the rearrangement of the 1-aza-15-hexadienyl anion (3a) to the 3-aza-1,5-hexadienyl anion (3b) may proceed by an exothermic, step-wise process with a relatively low activation energy.

引用

页码：7055 / 7056

页数：2

共 10 条

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