SYNTHESIS AND STRUCTURES OF PLATINUM(II) MIXED-LIGAND COMPLEXES WITH PURINE OR PYRIMIDINE-BASES OF DNA AND IMIDAZOLE DERIVATIVES .2.

被引：8

作者：

EFIMENKO, IA

KURBAKOVA, AP

MATOVIC, ZD

PONTICELLI, G

机构：

[1] RUSSIAN ACAD SCI, INST GEN & INORGAN CHEM, MOSCOW 117907, RUSSIA

[2] UNIV KRAGUJEVAC, FAC SCI, DEPT CHEM, YU-34000 KRAGUJEVAC, YUGOSLAVIA

[3] UNIV CAGLIARI, DIPARTIMENTO CHIM & TECNOL INORGAN & MET ORGAN, I-09124 CAGLIARI, ITALY

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 06期

关键词：

D O I：

10.1007/BF00980420

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Platinum(II) mixed ligand complexes with either purine or pyrimidine and imidazole derivatives were prepared and characterized by i.r., Raman and electronic spectroscopy. The compounds had the general formula [PtL(1)L(2)Cl(2)], where L(1) = adenine, guanine, hypoxanthine, cytosine, 2-aminopyrimidine; L(2) = N-methylimidazole, N-ethylimidazole or N-propylimidazole. The platinum(II) complexes had a square planar structure with cts-halogens. Purine or pyrimidine and imidazole derivatived bases acted as monodentate ligands coordinated via the N(7) of purine and N(3) of pyrimidine and imidazole derivatives.

引用

页码：640 / 642

页数：3

共 14 条

[1] SPECTROSCOPIC AND BIOLOGICAL STUDIES ON PALLADIUM(II) COMPLEXES WITH N-ETHYL AND N-PROPYLIMIDAZOLE [J].