PHASE-STABILITY LIMITS OF BI2SR2CA1CU2O8+DELTA AND BI2SR2CA2CU3O10+DELTA

被引:73
作者
RUBIN, LM
ORLANDO, TP
VANDERSANDE, JB
GORMAN, G
SAVOY, R
SWOPE, R
BEYERS, R
机构
[1] IBM CORP,DIV RES,ALMADEN RES CTR,SAN JOSE,CA 95120
[2] MIT,DEPT ELECT ENGN & COMP SCI,CAMBRIDGE,MA 02139
关键词
D O I
10.1063/1.108335
中图分类号
O59 [应用物理学];
学科分类号
摘要
We determined the phase stability limits of Bi2Sr2Ca1Cu2O8+delta and Bi2Sr2Ca2Cu3O10+delta in the temperature range 650-880-degrees-C using a solid-state electrochemical technique. These phases decompose by incongruent melting above approximately 790-degrees-C, whereas they decompose by a solid-state reaction at lower temperatures. The solid-state decomposition reaction is reversible for Bi2Sr2Ca1Cu2O8+delta, but not for Bi2Sr2Ca2Cu3O10+delta.
引用
收藏
页码:1977 / 1979
页数:3
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