FORMATION, CHARACTERIZATION AND SINTERING OF ALKOXY-DERIVED BISMUTH VANADATE

被引：109

作者：

HIROTA, K ^{[1
]}

KOMATSU, G ^{[1
]}

YAMASHITA, M ^{[1
]}

TAKEMURA, H ^{[1
]}

YAMAGUCHI, O ^{[1
]}

机构：

[1] DOSHISHA UNIV,FAC ENGN,ELECTROCHEM LAB,KYOTO 602,JAPAN

来源：

MATERIALS RESEARCH BULLETIN | 1992年 / 27卷 / 07期

关键词：

ALKOXIDES; BISMUTH; VANADATES;

D O I：

10.1016/0025-5408(92)90177-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Monoclinic BiVO4 is formed by the hydrolysis of bismuth and vanadyl double alkoxide, followed by washing and drying. Its average particle size is almost-equal-to 45 nm. The chemical structure is described by the formula Bi(VO4). Sintered pellets with nearly theoretical density are prepared by hot pressing for 2 h at 750-degrees-C and 29.4 MPa. The electrical conductivity of the pellets has been measured at 150-degrees to 550-degrees-C. Data are interpreted in terms of ionic conductivity due to oxygen ion vacancies.

引用

页码：823 / 830

页数：8