PROCESS FOR MANUFACTURING 1,4-BUTANEDIOL FROM ACROLEIN

被引：8
作者：
ICHIKAWA, S
OHGOMORI, Y
SUMITANI, N
HAYASHI, H
IMANARI, M
机构：
[1] Tsukuba Research Center, Mitsubishi Petrochemical Co., Ltd., Ami, Ibaraki 300-03
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1995年 / 34卷 / 03期
关键词：
D O I：
10.1021/ie00042a034
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
1,4-Butanediol was obtained in high yield by hydroformylation of acrolein acetal in the presence of the Rh-diphosphine catalysts, followed by subsequent hydrolysis/hydrogenatian of the products over Ru and heteropolyacid catalysts supported on carbon. 2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) butane was found to be a highly efficient ligand in the above hydroformylation reaction to produce the desired intermediate to 1,4-butanediol. Preliminary cost evaluation revealed that the method presented in this paper is promising for industrial application.
引用
收藏
页码：971 / 973
页数：3
相关论文
共 12 条
[1]   ASYMMETRICAL HYDROGENATION IN PRESENCE OF CHIRAL DIPHOSPHINES [J].
AVIRONVIOLET, P ;
VARAGNAT, J ;
COLLEUILLE, Y .
JOURNAL OF MOLECULAR CATALYSIS, 1979, 5 (01) :41-50
[2]  
BOTTEGHI C, 1985, SYNTHESIS-STUTTGART, P592
[3]  
BROWNSTEIN AM, 1977, HYDROCARB PROCESS, V56, P159
[4]   DIPHOSPHINES WITH NATURAL BITE ANGLES NEAR 120-DEGREES INCREASE SELECTIVITY FOR NORMAL-ALDEHYDE FORMATION IN RHODIUM-CATALYZED HYDROFORMYLATION [J].
CASEY, CP ;
WHITEKER, GT ;
MELVILLE, MG ;
PETROVICH, LM ;
GAVNEY, JA ;
POWELL, DR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (14) :5535-5543
[5]  
Devon T. J., 1987, U.S. Patent, Patent No. [4,694,109 A, 4694109]
[6]  
HUGHES OR, 1977, Patent No. 4003918
[7]   ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .1. CATALYTIC SYSTEM OF RHODIUM(I) WITH (-)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE - NEW CHIRAL DIPHOSPHINE [J].
KAGAN, HB ;
DANG, TP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) :6429-&
[8]  
MATSUMOTO M, 1985, Patent No. 129802
[9]  
NAPOLITANO E, 1986, SYNTHESIS-STUTTGART, P122
[10]   BINAP-RUTHENIUM(II) DICARBOXYLATE COMPLEXES - NEW, HIGHLY EFFICIENT CATALYSTS FOR ASYMMETRIC HYDROGENATIONS [J].
OHTA, T ;
TAKAYA, H ;
NOYORI, R .
INORGANIC CHEMISTRY, 1988, 27 (03) :566-569
12