SYNTHESIS OF A 2H-AZIRINE BY [1+2]-CYCLOADDITION OF A PHOSPHINOCARBENE WITH A NITRILE AND ITS RING-EXPANSION TO A 1,2-LAMBDA(5)-AZAPHOSPHETE

被引：50

作者：

ALCARAZ, G ^{[1
]}

WECKER, U ^{[1
]}

BACEIREDO, A ^{[1
]}

DAHAN, F ^{[1
]}

BERTRAND, G ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

CARBENES; CYCLOADDITIONS; HETEROCYCLES; PHOSPHORUS COMPOUNDS;

D O I：

10.1002/anie.199512461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of carbene reaction is observed with the stable phosphinocarbene 1. It reacts with benzonitrile to give the 2H‐azirine 2, which in dichloromethane is converted into the 1,2λ5‐azaphosphete 3 after addition of a catalytic amount of dichloro(p‐cymene)ruthenium(II). R = (c‐C6H11)2N. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1246 / 1248

页数：3

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