ANALYSIS OF ARCHAEOLOGICAL POTTERY BY X-RAY-FLUORESCENCE SPECTROMETRY APPLYING THE LIMIT DILUTION METHOD

被引：7

作者：

CARBO, MTD ^{[1
]}

REIG, FB ^{[1
]}

ADELANTADO, JVG ^{[1
]}

MARTINEZ, VP ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC CHEM,DEPT ANALYT CHEM,E-46100 BURJASSOT,SPAIN

来源：

X-RAY SPECTROMETRY | 1994年 / 23卷 / 02期

关键词：

D O I：

10.1002/xrs.1300230203

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A method for correcting the intensity of x-ray fluorescence (limit dilution method) is proposed for the analysis of samples with a complex matrix such as ceramic materials of archaeological interest. This method corrects the interelement effects, resolving the wide deviations which occur in the quantitative results obtained by x-ray fluorescence without correction. The contents of sodium, magnesium, aluminium, silicon, potassium, calcium, titanium and iron in sixteen archaeological ceramic samples of different origins and from different locations were determined. The results obtained are comparable to the values obtained by chemical analysis. A statistical study of the data was carried out to classify the samples hierarchically by cluster analysis of their chemical composition and loss on ignition.

引用

页码：53 / 58

页数：6

共 27 条

[1] INTERNAL STANDARDS IN FLUORESCENT X-RAY SPECTROSCOPY
ADLER, I
AXELROD, JM
[J]. SPECTROCHIMICA ACTA, 1955, 7 (02): : 91 - 99
[2] IMPROVEMENTS IN X-RAY EMISSION ANALYSIS OF CEMENT RAW MIX
ANDERMANN, G
[J]. ANALYTICAL CHEMISTRY, 1961, 33 (12) : 1689 - &
[3] CALIBRATION METHOD FOR X-RAY FLUORESCENCE SPECTROMETRY
BEATTIE, HJ
BRISSEY, RM
[J]. ANALYTICAL CHEMISTRY, 1954, 26 (06) : 980 - 983
[4] BENNET H, 1971, CHEM METHODS SILICAT, P47
[5] INTENSITY RATIO TECHNIQUE FOR X-RAY SPECTROMETRIC ANALYSIS OF BINARY SAMPLES - PARTICULAR APPLICATION TO DETERMINATION OF NIOBIUM + TIN ON NB3SN-COATED METAL RIBBON
BERTIN, EP
[J]. ANALYTICAL CHEMISTRY, 1964, 36 (04) : 826 - &
[6] COMPARISON OF THE STATISTICAL TREATMENT OF RESULTS USING CONCENTRATIONS OF ELEMENTS DETERMINED BY NEUTRON-ACTIVATION AND X-RAY-FLUORESCENCE ANALYSIS-METHODS
BIRGUL, O
DIKSIC, M
YAFFE, L
[J]. JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1980, 55 (01): : 101 - 109
[7] De Jongh W.K., 1973, STAINLESS STEEL XRAY, V2, P151, DOI 10.1002/xrs.1300020404
[8] DIXON WJ, 1985, BMDP STATISTICAL SOF
[9] FLUORESCENT X-RAY SPECTRAL ANALYSIS OF POWDERED SOLIDS BY MATRIX DILUTION
GUNN, EL
[J]. ANALYTICAL CHEMISTRY, 1957, 29 (02) : 184 - 189
[10] HERBERT H, 1992, FRESENU J ANAL CHEM, V344, P178

← 1 2 3 →