KINETICS OF CYCLOADDITION OF TETRAFLUOROETHYLENE TO DICYCLOPENTADIENE

被引：2

作者：

CHRISTOVA, NB

PAVLOVA, SD

KOSTOV, GK

机构：

[1] Department of Polymers, Bourgas Technological University, Bourgas

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1993年 / 49卷 / 02期

关键词：

D O I：

10.1007/BF02067708

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The title reaction has been investigated in the formation of tetrafluorohept-2-ene in the temperature range from 443 to 473 K and at various molar ratios of tetrafluoroethylene and dicyclopentadiene. Kinetic studies support second and first order for the cycloaddition to both reagents. Least-squares analysis of the data yields the rate equation: r(A) = 26.11 x 10(11.4)exp [-118560/RT] c(CPD)2c(TFE)2[mol L-1min-1]

引用

页码：393 / 402

页数：10

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