COMPLEXES WITH POLAR W-W MULTIPLE BONDS - [W-2(OIPR)(4)L(DMPE)(2)] (L=(H)(2), CO) AND [W-2(O)(4)(MU-O)(W(CO)(DMPE)(2))(2)]

被引：7

作者：

CHISHOLM, MH ^{[1
]}

KRAMER, KS ^{[1
]}

STREIB, WE ^{[1
]}

机构：

[1] INDIANA UNIV,CTR MOLEC STRUCT,BLOOMINGTON,IN 47405

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期

关键词：

COMPLEXES WITH OXYGEN LIGANDS; COMPLEXES WITH PHOSPHORUS LIGANDS; METAL-METAL BONDS; TUNGSTEN COMPOUNDS;

D O I：

10.1002/anie.199508911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unsupported WW multiple bond between centers having different oxidation states is found in the homonuclear complex 1, which is formed from [W2(OiPr)4(iBu)2], a complex containing a WW bond. Dimers of this kind with mixed oxidation states arise because tungsten can bind hard as well as soft ligands. Such complexes should display interesting reactivity. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：891 / 893

页数：3

共 7 条

[1]

Chisholm M.F., UNPUB

[2] AN UNBRIDGED TRIPLE BOND UNITING D6 MO(0) AND D2 MO(IV) ATOMS - MO2(O-I-PR)4(DMPE)2 [J].