ABNORMAL REACTIONS OF OVERCROWDED TRIS(ARYLCHALCOGENO)SILYL CHLORIDES WITH SILVER PERCHLORATE

被引：3

作者：

TOKITOH, N ^{[1
]}

IMAKUBO, T ^{[1
]}

OKAZAKI, R ^{[1
]}

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,7-3-1 HONGO,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 39期

关键词：

SILICENIUM ION; KINETIC STABILIZATION; REARRANGEMENT; TRIS(ARYLCHALCOGENO)SILYL CHLORIDE; SILVER PERCHLORATE;

D O I：

10.1016/0040-4039(92)89040-J

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sterically congested tris(arylchalcogeno)silyl chlorides were synthesized, and their reactions with silver perchlorate afforded unexpected products with a rearranged skeleton which were most likely formed via intermediary tris (arylchalcogeno)silicenium perchlorates.

引用

页码：5819 / 5822

页数：4

共 18 条

[1] 1ST DEMONSTRATION OF SOLVOLYTIC GENERATION OF A SIMPLE SILICENIUM ION (R3SI+) - ACCESS VIA 1,2-METHYL MIGRATION [J].

APELOIG, Y ;

STANGER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) :272-273

[2] DOUBLE BONDING BETWEEN THE HEAVIER MAIN-GROUP ELEMENTS - FROM REACTIVE INTERMEDIATES TO ISOLABLE MOLECULES [J].

COWLEY, AH .

POLYHEDRON, 1984, 3 (04) :389-432

[3] A CONTRIBUTION TO THE SILICENIUM ION DEBATE [J].

EABORN, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 405 (02) :173-177

[4] 2 DIMERS DERIVED FROM THE 2,4,6-TRI-TERT-BUTYLPHENYL RADICAL, FORMED DURING REACTIONS OF THE ARYLLITHIUM OR THE GRIGNARD-REAGENT WITH CARBONYL-COMPOUNDS [J].

FREY, J ;

NUGIEL, DA ;

RAPPOPORT, Z .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (01) :466-469

[5] CHEMISTRY OF N-THIOSULFINYLANILINES .5. REACTIONS OF N-THIOSULFINYLANILINES WITH NUCLEOPHILIC-REAGENTS [J].

INAGAKI, Y ;

HOSOGAI, T ;

OKAZAKI, R ;

INAMOTO, N .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (01) :205-209

[6] CHEMISTRY OF ORGANOSILICON COMPOUNDS .294. SILOXYCARBENIUM TETRAKIS[3,5-BIS(TRIFLUOROMETHYL)PHENYL]BORATES AND THEIR ROLE IN REACTIONS OF KETONES WITH NUCLEOPHILES [J].

KIRA, M ;

HINO, T ;

SAKURAI, H .

CHEMISTRY LETTERS, 1992, (04) :555-558

[7] THE 1ST SILYLENIUM IONS IN SOLUTION [J].

LAMBERT, JB ;

SCHULZ, WJ ;

MCCONNELL, JA ;

SCHILF, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (07) :2201-2210

[8] TRIMETHYLSILYL AND RELATED CATIONS IN SOLUTION [J].

LAMBERT, JB ;

KANIA, L ;

SCHILF, W ;

MCCONNELL, JA .

ORGANOMETALLICS, 1991, 10 (08) :2578-2584

[9] KINETICS OF HYDRIDE TRANSFER-REACTIONS FROM HYDROSILANES TO CARBENIUM IONS - SUBSTITUENT EFFECTS IN SILICENIUM IONS [J].

MAYR, H ;

BASSO, N ;

HAGEN, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :3060-3066

[10] ABNORMAL REACTIONS OF STERICALLY BULKY ORGANOMETALLICS ARM (AR=2,4,6-TRI-TERT-BUTYLPHENYL, M=LI OR MGBR) WITH LEAD DICHLORIDE [J].

OKAZAKI, R ;

SHIBATA, K ;

TOKITOH, N .

TETRAHEDRON LETTERS, 1991, 32 (45) :6601-6604

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