INTRAMOLECULAR CYCLIZATION OF 2'-OLEFINIC SIDE-CHAINS ON ANODICALLY OXIDIZED 4-PHENYLPHENOLS - THE EFFECT OF OLEFIN SUBSTITUENTS ON CARBON-CARBON BOND FORMATION

被引：20

作者：

MORROW, GW ^{[1
]}

CHEN, Y ^{[1
]}

SWENTON, JS ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,120 W 18TH AVE,COLUMBUS,OH 43210

来源：

TETRAHEDRON | 1991年 / 47卷 / 4-5期

关键词：

D O I：

10.1016/S0040-4020(01)87055-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anodic oxidation of 4-(2'-alkenylphenyl)phenols in acetonitrile/methanol affords spirodienones arising from cyclization of the olefinic side-chain to the 4-position of the phenol and reaction of the resulting benzylic cation with methanol. The efficiency of this carbon-carbon bond-forming reaction is dependent upon the olefinic substituents.

引用

页码：655 / 664

页数：10

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