ONE-ELECTRON REDOX REACTIONS OF COASH ESTERS IN ANAEROBIC-BACTERIA - A MECHANISTIC PROPOSAL

被引：62

作者：

BUCKEL, W ^{[1
]}

KEESE, R ^{[1
]}

机构：

[1] UNIV BERN,INST ORGAN CHEM,CH-3012 BERN,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

BIOCHEMISTRY; COENZYME A; REACTION MECHANISMS; REDOX REACTIONS;

D O I：

10.1002/anie.199515021

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ketyl intermediates in unusual enzymatic reactions in anaerobic bacteria may possibly be generated by one‐electron reductions of thioesters (coenzyme‐A esters). One example is the reversible syn‐dehydration of (R)‐2‐hydroxyglutaryl‐CoA via 1 to give (E)‐glutaconyl‐CoA. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1502 / 1506

页数：5

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