2-STEP STEREOSELECTIVE CONVERSION OF 5-MONOSUBSTITUTED 1,3-DIOXOLAN-4-ONES INTO SELECTIVELY PROTECTED 2,3-ERYTHRO-1,2,3-TRIOLS - A ROUTE TO POLYHYDROXYLATED MOLECULES

被引：12

作者：

UNTERSTELLER, E ^{[1
]}

XIN, YC ^{[1
]}

SINAY, P ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CNRS,DEPT CHIM,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 16期

关键词：

1,3-DIOXOLAN-4-ONE DERIVATIVES; TEBBE METHYLENATION; POLYOLS;

D O I：

10.1016/S0040-4039(00)77164-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

5-Monosubstituted 1,3-dioxolan-4-one 1 are stereoselectively converted into selectively protected 2,3-erythro-1,2,9-triols 3 via Tebbe methylenation, followed by hydroboration-oxidation.

引用

页码：2537 / 2540

页数：4