CONSTRUCTION OF HIGHLY EFFICIENT MN-SALEN CATALYST FOR ASYMMETRIC EPOXIDATION OF CONJUGATED CIS-OLEFINS

被引：0
|
作者：
SASAKI, H [1 ]
IRIE, R [1 ]
KATSUKI, T [1 ]
机构：
[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN
来源：
SYNLETT | 1994年 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
On the basis of the newly proposed hypothesis on the olefin's approach to metal-oxo species, highly efficient (salen)manganese(III) complex (3) was synthesized as a catalyst for asymmetric epoxidation. With this catalyst, the highest level of enantioselectivity was realized in the epoxidation of conjugated cis-olefins.
引用
收藏
页码：356 / 358
页数：3
相关论文
共 50 条
  • [41] Ionic liquid-functionalized graphene oxide as an efficient support for the chiral salen Mn(III) complex in asymmetric epoxidation of unfunctionalized olefins
    Zheng, Weiguo
    Tan, Rong
    Yin, Shenfu
    Zhang, Yaoyao
    Zhao, Guangwu
    Chen, Yaju
    Yin, Donghong
    CATALYSIS SCIENCE & TECHNOLOGY, 2015, 5 (04) : 2092 - 2102
  • [42] Epoxidation of unfunctionalized olefins by Mn(salen) catalyst using organic peracids as oxygen source: A theoretical study
    Khavrutskii, IV
    Musaev, DG
    Morokuma, K
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2004, 101 (16) : 5743 - 5748
  • [43] P-2-NICKEL CATALYST WITH ETHYLENEDIAMINE, A NOVEL SYSTEM FOR HIGHLY STEREOSPECIFIC REDUCTION OF ALKYNES TO CIS-OLEFINS
    BROWN, CA
    AHUJA, VK
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (15) : 553 - 554
  • [44] Polyglycerol-supported Co- and Mn-salen complexes as efficient and recyclable homogeneous catalysts for the hydrolytic kinetic resolution of terminal epoxides and asymmetric olefin epoxidation
    Beigi, Maryam
    Roller, Sebastian
    Haag, Rainer
    Liese, Andreas
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (12) : 2135 - 2141
  • [45] Design of a highly efficient catalyst for the oxaziridinium-mediated epoxidation of olefins by Oxone®
    Bohé, L
    Kammoun, M
    TETRAHEDRON LETTERS, 2004, 45 (04) : 747 - 751
  • [46] Organic carbonates as solvents in macrocyclic Mn(III) salen catalyzed asymmetric epoxidation of non-functionalized olefins
    Maity, Nabin Ch
    Rao, Ganga V. S.
    Prathap, K. J.
    Abdi, Sayed H. R.
    Kureshy, Rukhsana I.
    Khan, Noor-ul H.
    Bajaj, Hari C.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 366 : 380 - 389
  • [47] Recoverable Mn~Ⅲ (salen) supported on diamine modified zirconium poly(styrene-isopropenyl phosphonate)-phosphate as an efficient catalyst for epoxidation of unfunctionalized olefins
    ZOU XiaoChuan 1*
    Key Laboratory of Applied Chemistry of Chongqing Municipality
    Key Laboratory of Eco-environments in Three Gorges Reservoir Region Ministry of Education
    Science China(Chemistry), 2012, (11) : 2397 - 2407
  • [48] Chiral salen Mn (III) immobilized on ZnPS-PVPA through alkoxyl-triazole for superior performance catalyst in asymmetric epoxidation of unfunctionalized olefins
    Huang, Jing
    Liu, Sirui
    Ma, Yan
    Cai, Jiali
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2019, 886 : 27 - 33
  • [49] Synthesis of new immobilized chiral Salen Mn (III) complex as effective catalyst for asymmetric epoxidation of styrene
    Bao He-Bin
    Fu Xiang-Kai
    Bai Ruo-Fei
    Ren Wen-Shan
    Tu Xiao-Bo
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2008, 29 (05): : 927 - 931
  • [50] Asymmetric Epoxidation of cis/trans-β-Methylstyrene Catalysed by Immobilised Mn(Salen) with Different Linkages: Heterogenisation of Homogeneous Asymmetric Catalysis
    Zhang, Haidong
    Zou, Yu
    Wang, Yi-Meng
    Shen, Yu
    Zheng, Xuxu
    CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (25) : 7830 - 7841
12345