MIXED-VALENCE STATES IN TCNQ SALTS OF MONOALKYLBIFERROCENES AND THEIR MIXED-CRYSTALS WITH DIALKYL DERIVATIVE

被引：6
|
作者：
NAKASHIMA, S [1 ]
KOURA, T [1 ]
KATADA, M [1 ]
SANO, H [1 ]
MOTOYAMA, I [1 ]
机构：
[1] KANAGAWA UNIV,FAC ENGN,DEPT CHEM,KANAGAWA KU,YOKOHAMA 221,JAPAN
来源：
HYPERFINE INTERACTIONS | 1990年 / 53卷 / 1-4期
关键词：
D O I：
10.1007/BF02101067
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
TCNQ salts of 1′-monoalkylbiferrocenes showed a temperature-independent trapped-valence state as expected for the unsymmetrical structure of cations. On the other hand, mixed crystals of 1′-monobutyl- and 1′.1‴-dibutylbiferrocenium+(TCNQ)3- showed a temperature dependence of the mixed-valence states, showing that the lattice affects the mixed-valence states. © 1990 J.C. Baltzer AG, Scientific Publishing Company.
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页码：361 / 366
页数：6
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