VANADYL COMPLEXES IN AMBIENT-TEMPERATURE IONIC LIQUIDS - THE 1ST X-RAY CRYSTAL-STRUCTURE OF A TETRACHLOROOXOVANADATE(IV) SALT

被引：34

作者：

HITCHCOCK, PB

LEWIS, RJ

WELTON, T

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4RJ,DEVON,ENGLAND

[2] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)81478-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel salt [emim]2[VOCl4] ([emim]+ = 1-ethyl-3-methylimidazolium cation) has been prepared and characterized, both spectroscopically and crystallographically. The [VOCl4]2 - anion has an approximately square pyramidal structure in the solid state. This structure is maintained when the salt is dissolved in the [emim]Cl-AlCl3 ambient-temperature ionic liquid.

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页码：2039 / 2044

页数：6

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