HOMOATOMIC POLYANIONS OF POSTTRANSITION ELEMENTS - SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF THE PARAMAGNETIC NONAGERMANIDE (3-) ION GE9(3-), A C2V CLUSTER WITH AN ODD SKELETAL ELECTRON COUNT

被引:22
作者
ANGILELLA, V
BELIN, C
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 01期
关键词
D O I
10.1039/ft9918700203
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The salt K3(2,2,2-cryptand)3(PPh3)3Ge9 has been obtained by complexation of the KGe1.8 alloy by 2,2,2-cryptand in ethylenediamine with solute triphenylphosphine. The structure of the anion has been determined crystallographically and the results are supported by EPR and extended Huckel calculations.
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页码:203 / 204
页数:2
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