HOMOATOMIC POLYANIONS OF POSTTRANSITION ELEMENTS - SYNTHESIS, STRUCTURE AND CHARACTERIZATION OF THE PARAMAGNETIC NONAGERMANIDE (3-) ION GE9(3-), A C2V CLUSTER WITH AN ODD SKELETAL ELECTRON COUNT

被引：22

作者：

ANGILELLA, V

BELIN, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1991年 / 87卷 / 01期

关键词：

D O I：

10.1039/ft9918700203

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The salt K3(2,2,2-cryptand)3(PPh3)3Ge9 has been obtained by complexation of the KGe1.8 alloy by 2,2,2-cryptand in ethylenediamine with solute triphenylphosphine. The structure of the anion has been determined crystallographically and the results are supported by EPR and extended Huckel calculations.

引用

页码：203 / 204

页数：2

共 15 条

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