ANOMALOUS REACTIVITY OF MONO SUBSTITUTED RHODIUM STABILIZED VINYLCARBENOIDS

被引：61

作者：

DAVIES, HML

SAIKALI, E

CLARK, TJ

CHEE, EH

机构：

[1] Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97047-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In contrast to rhodium(lI) stabilized vinylcarbenoids with two electron withdrawing groups, the related mono substituted vinylcarbenoids exhibit reactivity at either the carbenoid center or the vinylogous position. The site of reactivity may be controlled by appropriate catalysts and solvents, leading to the effective synthesis of bicyclic systems by a tandem cyclopropanation/Cope rearrangement sequence. © 1990.

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页码：6299 / 6302

页数：4

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