Ceramics based on BaTi4O9 and Ba2Ti9O20 have been largely ignored over the past decade by manufacturers of high Q, high dielectric constant, temperature compensated materials for commercial wireless communications at elevated frequencies. When processed correctly, these ceramics yield properties that rival if not exceed those of ZrTiO4-based products currently used. Materials incorporating ZnO/Me2O5 (Me = Talpha, Nb) and their properties are described.