SYNTHESIS OF A CROWN-ETHER FUNCTIONALIZED PHOSPHINE AND ITS NICKEL(II), PALLADIUM(II) AND PLATINUM(II) COMPLEXES

被引：11

作者：

SERINDAG, O

机构：

[1] Çukurova University Science and Arts Faculty, Chemistry Department

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1995年 / 25卷 / 02期

关键词：

D O I：

10.1080/15533179508218223

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of 4'-aminobenzo-15-crown-5 (1) (Figure 1) with diphenylphosphine in the presence of formaldehyde or with the phosphonium salt [Ph(2)P(CH2OH)(2)]Cl in the presence of triethylamine gives a novel aminomethylphosphine (2). Nickel(II), palladium(II) and platinum(II) complexes of (2) have been synthesized and characterized by means of their P-31 and H-1 NMR and mass spectra and microanalytical data.

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页码：327 / 335

页数：9

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