ASYMMETRIC HYDROGENATION OF PROCHIRAL CARBOXYLIC-ACIDS AND FUNCTIONALIZED CARBONYL-COMPOUNDS CATALYZED BY RUTHENIUM(II)-BINAP COMPLEXES WITH ARYL NITRILES (BINAP = (R)-S,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL OR (S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL)

被引：31

作者：

SHAO, LM ^{[1
]}

TAKEUCHI, K ^{[1
]}

IKEMOTO, M ^{[1
]}

KAWAI, T ^{[1
]}

OGASAWARA, M ^{[1
]}

TAKEUCHI, H ^{[1
]}

KAWANO, H ^{[1
]}

SABURI, M ^{[1
]}

机构：

[1] UNIV TOKYO,FAC ENGN,DEPT IND CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 435卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(92)83466-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes RuCl2(ArCN)2(binap), II (binap = (R)- or (S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl; ArCN = benzonitrile, a; 2-furancarbonitrile, b; pentafluorobenzonitrile, c) were prepared, and their solution properties were investigated by P-31 NMR measurements. The catalytic activities and enantioselectivities for IIa-c catalysed hydrogenation of some prochiral acids were very similar to those provided by Ru2Cl4(binap)2(NEt3), I. In the hydrogenation of beta-functionalized carbonyl compounds, however, IIa-c showed considerably lower activities and/or selectivities, compared with complex I. The differences in IIa-c catalysed reactions are discussed in relation to the coordinating abilities of ArCN in II.

引用

页码：133 / 147

页数：15

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