PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS OF VINYL AND ARYL TRIFLATES WITH TETRAARYLBORATES

被引：60

作者：

CIATTINI, PG

MORERA, E

ORTAR, G

机构：

[1] UNIV ROME LA SAPIENZA,DIPARTIMENTO STUDI FARMACEUT,I-00185 ROME,ITALY

[2] UNIV ROME LA SAPIENZA,CNR,CTR STUDIO CHIM FARMACO,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 33期

关键词：

D O I：

10.1016/S0040-4039(00)61293-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium tetraarylborates 2 have been found to couple efficiently with vinyl and aryl triflates 1 in the presence of a palladium(0) catalyst to afford arylalkenes and biaryls 3 in good yields and under mild conditions.

引用

页码：4815 / 4818

页数：4

共 17 条

[1]

ARCADI A, 1990, SYNLETT, P47

[2]

CATELLANI M, 1990, GAZZ CHIM ITAL, V120, P779

[3] A NEW SYNTHESIS OF THE CORTICOSTEROID SIDE-CHAIN [J].

CIATTINI, PG ;

MORERA, E ;

ORTAR, G .

TETRAHEDRON LETTERS, 1990, 31 (13) :1889-1892

[4] CONNECTIONS TO THE DIRECTED ORTHO METALATION STRATEGY - PD(0)-CATALYZED CROSS COUPLING OF ARYL BORONIC ACIDS WITH ARYL TRIFLATES [J].

FU, JM ;

SNIECKUS, V .

TETRAHEDRON LETTERS, 1990, 31 (12) :1665-1668

[5] STEREOCHEMISTRY OF THE CROSS-COUPLING REACTION OF CHIRAL ALKYLSILANES WITH ARYL TRIFLATES - A NOVEL-APPROACH TO OPTICALLY-ACTIVE COMPOUNDS [J].

HATANAKA, Y ;

HIYAMA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (21) :7793-7794

[6] GAMMA-SELECTIVE CROSS-COUPLING REACTION OF ALLYLTRIFLUOROSILANES - A NEW APPROACH TO REGIOCHEMICAL CONTROL IN ALLYLIC SYSTEMS [J].

HATANAKA, Y ;

EBINA, Y ;

HIYAMA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7075-7076

[7] A WIDE-RANGE OF ORGANOSILICON COMPOUNDS COUPLES WITH ENOL AND ARYL TRIFLATES IN THE PRESENCE OF PD CATALYST AND FLUORIDE-ION [J].

HATANAKA, Y ;

HIYAMA, T .

TETRAHEDRON LETTERS, 1990, 31 (19) :2719-2722

[8] PALLADIUM-CATALYZED CROSS-COUPLING REACTION OF TRIALKYLALUMINUMS WITH ARYL TRIFLATES - FACILE CONVERSION OF A PHENOLIC HYDROXY GROUP INTO AN ALKYL GROUP [J].

HIROTA, K ;

ISOBE, Y ;

MAKI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (12) :2513-2514

[9] SYNTHESIS OF DIARYLIC COMPOUNDS BY PALLADIUM CATALYZED REACTION OF AROMATIC TRIFLATES WITH BORONIC ACIDS [J].

HUTH, A ;

BEETZ, I ;

SCHUMANN, I .

TETRAHEDRON, 1989, 45 (21) :6679-6682

[10] PALLADIUM-CATALYZED PHENYLATION OF ALLYLIC ACETATES BY TETRAPHENYLBORATE ANION [J].

LEGROS, JY ;

FIAUD, JC .

TETRAHEDRON LETTERS, 1990, 31 (51) :7453-7456

← 1 2 →