POLARIZED LUMINESCENCE FROM DIVALENT S-2 ION-CATION VACANCY COMPLEXES IN POTASSIUM HALIDE SINGLE-CRYSTALS

被引:3
|
作者
SCACCO, A
JACOBS, PWM
BELLIVEAU, TF
KANG, JG
SIMKIN, DJ
机构
[1] UNIV WESTERN ONTARIO,DEPT CHEM,LONDON N6A 3K7,ONTARIO,CANADA
[2] MCGILL UNIV,DEPT CHEM,MONTREAL H3A 2T5,QUEBEC,CANADA
关键词
CRYSTALS; -; Defects; LUMINESCENCE;
D O I
10.1016/0022-2313(84)90229-1
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The polarized luminescence of KX:Sn**2** plus (X equals Br,I) and KY:Pb**2** plus (Y equals Cl,Br,I) after A band excitation, is discussed. The angular dependence of polarization indicates that these centers possess tetragonal symmetry. In KX:Sn**2** plus , where JT greater than equivalent to SO, the temperature dependence of the polarization is explained by considering the perturbing effect of an nnn v//c** minus on the JT wells. In KY:Pb**2** plus , where SO greater than equivalent to JT, all features of the polarization are explained in terms of an impurity ion-v//c** minus dipole oriented along a C//4 axis (nnn v//c** minus , tetragonal).
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页码:145 / 147
页数:3
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