CATIONIC, NEUTRAL, AND ANIONIC ORGANOALUMINUM SPECIES IN [ALME(2)(18-CROWN-6)ALME(2)X][ALMEX(3)] (X=CL, I)

被引：9
作者：
ATWOOD, JL
BOTT, SG
HARVEY, S
JUNK, PC
机构：
[1] Department of Chemistry, University of Missouri—Columbia, Columbia
来源：
ORGANOMETALLICS | 1994年 / 13卷 / 11期
关键词：
D O I：
10.1021/om00023a010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
18-crown-6 reacts with AlX(3) (X = Cl, 1, X = I, 2) in an ex cess of AlMe(3) in toluene to form the liquid clathrate species [AlMe(2)(18-crown-6)AlMe(2)X][AlMeX(3)]. The AlMe(2)(+) ion is coordinated to the interior of the macrocycle, while the neutral species is coordinated to the exterior, via an inverted crown oxygen atom.
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页码：4151 / 4152
页数：2
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