ON THE HYDROZIRCONATION OF 4,4-DIMETHYL-2-OXAZOLINES OF SOME ALPHA,BETA-UNSATURATED, BETA,GAMMA-UNSATURATED AND GAMMA,DELTA-UNSATURATED FATTY-ACIDS

被引：0
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作者：
ALVHALL, J
GRONOWITZ, S
HALLBERG, A
SVENSON, R
机构：
来源：
CHEMICA SCRIPTA | 1984年 / 24卷 / 4-5期
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中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A series of 4,4-dimethyl-2-oxazolines of .alpha., .beta.-, .beta., .gamma.- and .gamma.,.delta.-unsaturated fatty acids were treated with bis(.pi.-cyclopentadienyl)-zirconiumhydrido chloride. The .alpha.-, b- and .omega.-zirconium intermediates formed in the reactions were relatively stable and were trapped by deuteriation. The isomer distribution, determined by 13C and/or 2H-NMR spectroscopy, was very dependent on the position of the double bond in the starting material. The oxazoline of cis octenoic acid was found to be a good model for the corresponding oleic acid derivative. Oxazolines of .alpha.,.beta.-unsaturated carboxylic acids unsubstituted in the .beta.-position gave predominantly non-deuteriated saturated compounds.
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页码：170 / 177
页数：8
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