1,5-INTRAMOLECULAR VS 1,6-INTRAMOLECULAR HOMOLYTIC AROMATIC-SUBSTITUTION BY VINYL RADICALS

被引：32

作者：

CITTERIO, A ^{[1
]}

SEBASTIANO, R ^{[1
]}

MARONATI, A ^{[1
]}

SANTI, R ^{[1
]}

BERGAMINI, F ^{[1
]}

机构：

[1] IST GUIDO DONEGANI SPA,I-28100 NOVARA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 13期

关键词：

D O I：

10.1039/c39940001517

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese(III) acetate oxidation of substituted diethyl benzylmalonates in the presence of alkynes affords tetrahydronaphthalene derivatives 3, 6, 7 and spiro [4,5]decatriene derivatives 4 or 5, through competitive 1,5 and 1,6 intramolecular aromatic substitution by vinyl radicals.

引用

收藏

页码：1517 / 1518

页数：2

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