HOMOGENEOUS-CATALYTIC ACETOXYLATION OF 1-HEXENE AND CYCLOHEXENE

被引：0
作者：
TRUSHOVA, NV
DEVEKKI, AV
机构：
来源：
PETROLEUM CHEMISTRY | 1992年 / 32卷 / 04期
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D O I：
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A study has been made of the acetoxylation of 1-hexene and cyclohexene in the presence of PdCl42- and a nitrate-iodate reoxidative system ensuring high yields of the corresponding acetoxyalkanes. It has been established that a binuclear pi-olefinic bridge-type palladium complex is a catalytically active particle. It is assumed that the mechanisms of formation of 1,2-hexanediol monoacetate and diacetoxycyclohexane differ at the final stage of transformation of the acetoxonium ion. Acetoxylation is retarded by the reaction products, which screen the coordination sphere of palladium.
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页码：313 / 319
页数：7
相关论文
共 14 条
  • [1] ANDERSON CB, 1963, J ORG CHEM, V28, P605
  • [2] DEVEKKI AV, 1981, ZH ORG KHIM+, V17, P2519
  • [3] DEVEKKI AV, 1989, ZH ORG KHIM+, V25, P1859
  • [4] DEVEKKI AV, 1980, ZH ORG KHIM+, V16, P2518
  • [5] DEVEKKI AV, 1987, NEFTEKHIMIYA, V27, P200
  • [6] Coordination compounds of palladous chloride
    Kharasch, MS
    Seyler, RC
    Mayo, FR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 : 882 - 884
  • [7] KHERBERKHOLD M, 1975, PICOMPLEXES METALS, P142
  • [8] LEBEDEVA EG, 1978, ZH ORG KHIM+, V14, P1589
  • [9] LEVANDA OG, 1968, ZH ORG KHIM, V4, P1533
  • [10] MITSUTANI A, 1973, CHEM ECON ENG REV, V5, P32
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