THE INVENTION OF RADICAL REACTIONS .24. RELATIVE RATES OF ACYLATION AND RADICAL DEOXYGENATION OF SECONDARY ALCOHOLS

被引：46
作者：
BARTON, DHR
DORCHAK, J
JASZBERENYI, JC
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON | 1992年 / 48卷 / 36期
关键词：
D O I：
10.1016/S0040-4020(01)90359-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Secondary alcohols were transformed into various thiocarbonyl derivatives. Reduction of these compounds using tributyltin hydride and an initiator afforded the corresponding deoxy-compounds. Half-life and competitive measurements showed that all these reactions were fast and could be run to completion.
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页码：7435 / 7446
页数：12
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