STUDY OF THE INFLUENCE OF THE LIQUID-CRYSTALLINE STATE ON THE CONFORMATIONAL STRUCTURE OF MACROMOLECULES

被引：0
作者：
SHILOV, SV
BIRSHTEIN, TM
VOLCHEK, BZ
GORYUNOV, AN
机构：
来源：
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A | 1991年 / 33卷 / 03期
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Conformations of the flexible spacer and average parameters of the order of spacer and mesogenic group have been calculated in the framework of the turn-isomeric approximation for LC polyesters having the mesogenic groups and spacers in the backbone. Comparison of obtained results with the data of IR-spectroscopy and X-ray analysis permits to conclude the essential elongation both of the monomer unit and the macromolecule as a whole.
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页码：659 / 667
页数：9
相关论文
共 15 条
[1]   ORIENTATIONAL CHARACTERISTICS OF MAIN-CHAIN POLYMER LIQUID-CRYSTALS AS REVEALED BY THE ROTATIONAL ISOMERIC STATE ANALYSIS OF DEUTERIUM NMR-SPECTRA [J].
ABE, A ;
FURUYA, H .
MACROMOLECULES, 1989, 22 (07) :2982-2987
[2]   CONFIGURATIONAL ASPECTS OF THE ODD-EVEN EFFECT IN THERMOTROPIC LIQUID-CRYSTALLINE POLYESTERS [J].
ABE, A .
MACROMOLECULES, 1984, 17 (11) :2280-2287
[3]   INHERENTLY FLEXIBLE THERMOTROPIC MAIN CHAIN POLYMERIC LIQUID-CRYSTALS [J].
BLUMSTEIN, RB ;
BLUMSTEIN, A .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 165 :361-387
[4]  
DEGENNES PG, 1977, POLYM PREPR AM CHEM, V18, P161
[5]  
FLORY P, 1984, ADV POLYM SCI, V59, P11
[6]   TRANSITIONS AND RELAXATIONS IN MESOPHASE POLYMERS - THERMOTROPIC LIQUID-CRYSTALLINE POLYESTERS WITH MESOGENIC GROUPS IN THE MAIN CHAIN [J].
FROSINI, V ;
DEPETRIS, S ;
CHIELLINI, E ;
GALLI, G ;
LENZ, RW .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1983, 98 (1-4) :223-242
[7]  
GRIGOREV AI, 1984, VYSOKOMOL SOEDIN B, V26, P591
[8]  
GRIGOREV AI, 1982, 1 VSES S ZHK POL CHE, P112
[9]  
KHOLMURADOV NS, 1983, THESIS AN SSSR LENIN
[10]  
OBER CK, 1983, MAKROMOL CHEM-RAPID, V4, P49
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