Dinuclear Lanthanide (III) Coordination Polymers in a Domino Reaction

被引：9

作者：

Loukopoulos, Edward ^{[1
]}

Griffiths, Kieran ^{[1
]}

Akien, Geoffrey R. ^{[2
]}

Kourkoumelis, Nikolaos ^{[3
]}

Abdul-Sada, Alaa ^{[1
]}

Kostakis, George E. ^{[1
]}

机构：

[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England

[2] Univ Lancaster, Dept Chem, Lancaster LA1 4YB, England

[3] Univ Ioannina, Sch Hlth Sci, Dept Med Phys, GR-45110 Ioannina, Greece

来源：

INORGANICS | 2015年 / 3卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination polymers; lanthanide; single crystal; Y-89-NMR; catalysis; domino reaction;

D O I：

10.3390/inorganics3040448

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A systematic study was performed to further optimise the catalytic room-temperature synthesis of trans-4,5-diaminocyclopent-2-enones from 2-furaldehyde and primary or secondary amines under a non-inert atmosphere. For this purpose, a series of dinuclear lanthanide (III) coordination polymers were synthesised using a dianionic Schiff base and their catalytic activities were investigated.

引用

页码：448 / 466

页数：19

共 51 条

[1] Fluorescent Naphthalene Diols as Bridging Ligands in LnIII Cluster Chemistry: Synthetic, Structural, Magnetic, and Photophysical Characterization of Ln8III "Christmas Stars" [J].

Alexandropoulos, Dimitris I. ;

Fournet, Adeline ;

Cunha-Silva, Luis ;

Mowson, Andrew M. ;

Bekiari, Vlasoula ;

Christou, George ;

Stamatatos, Theocharis C. .

INORGANIC CHEMISTRY, 2014, 53 (11) :5420-5422

[2] Using lanthanide ions in molecular bioimaging [J].

Amoroso, Angelo J. ;

Pope, Simon J. A. .

CHEMICAL SOCIETY REVIEWS, 2015, 44 (14) :4723-4742

[3] Dinuclear Lanthanide(III) Complexes by Metal-Ion-Assisted Hydration of Di-2-pyridyl Ketone Azine [J].

Anastasiadis, Nikolaos C. ;

Granadeiro, Carlos M. ;

Klouras, Nikolaos ;

Cunha-Silva, Luis ;

Raptopoulou, Catherine P. ;

Psycharis, Vassilis ;

Bekiari, Vlasoula ;

Balula, Salete S. ;

Escuer, Albert ;

Perlepes, Spyros P. .

INORGANIC CHEMISTRY, 2013, 52 (08) :4145-4147

[4] The exceptionally rich coordination chemistry generated by Schiff-base ligands derived from o-vanillin [J].

Andruh, Marius .

DALTON TRANSACTIONS, 2015, 44 (38) :16633-16653

[5] Structural aesthetics in molecular nanoscience: a unique Ni26 cluster with a 'rabbit-face' topology and a discrete Ni18 'molecular chain' [J].

Athanasopoulou, Angeliki A. ;

Pilkington, Melanie ;

Raptopoulou, Catherine P. ;

Escuer, Albert ;

Stamatatos, Theocharis C. .

CHEMICAL COMMUNICATIONS, 2014, 50 (95) :14942-14945

[6] Homodinuclear lanthanide {Ln2} (Ln = Gd, Tb, Dy, Eu) complexes prepared from an o-vanillin based ligand: luminescence and single-molecule magnetism behavior [J].

Bag, Prasenjit ;

Rastogi, Chandresh Kumar ;

Biswas, Sourav ;

Sivakumar, Sri ;

Mereacre, Valeriu ;

Chandrasekhar, Vadapalli .

DALTON TRANSACTIONS, 2015, 44 (09) :4328-4340

[7] A new family of high nuclearity CoII/DyIII coordination clusters possessing robust and unseen topologies [J].

Berkoff, Benjamin ;

Griffiths, Kieran ;

Abdul-Sada, Alaa ;

Tizzard, Graham J. ;

Coles, Simon J. ;

Escuer, Albert ;

Kostakis, George E. .

DALTON TRANSACTIONS, 2015, 44 (28) :12788-12795

[8] Thiacalix[4]arene-Supported Planar Ln4 (Ln = TbIII, DyIII) Clusters: Toward Luminescent and Magnetic Bifunctional Materials [J].

Bi, Yanfeng ;

Wang, Xiu-Teng ;

Liao, Wuping ;

Wang, Xinwu ;

Deng, Ruiping ;

Zhang, Hongjie ;

Gao, Song .

INORGANIC CHEMISTRY, 2009, 48 (24) :11743-11747

[9] On the design of highly luminescent lanthanide complexes [J].

Buenzli, Jean-Claude G. .

COORDINATION CHEMISTRY REVIEWS, 2015, 293 :19-47

[10] Octanuclear {Ln(III)8}(Ln = Gd, Tb, Dy, Ho) Macrocyclic Complexes in a Cyclooctadiene-like Conformation: Manifestation of Slow Relaxation of Magnetization in the Dy(III) Derivative [J].

Chandrasekhar, Vadapalli ;

Bag, Prasenjit ;

Colacio, Enrique .

INORGANIC CHEMISTRY, 2013, 52 (08) :4562-4570

← 1 2 3 4 5 6 →