SOLVENT EFFECTS ON THE MONOLAYER STRUCTURE OF LONG N-ALKANE MOLECULES ADSORBED ON GRAPHITE

被引：95

作者：

HERWIG, KW ^{[1
]}

MATTHIES, B ^{[1
]}

TAUB, H ^{[1
]}

机构：

[1] UNIV MISSOURI,MISSOURI UNIV RES REACTOR FACIL,COLUMBIA,MO 65211

来源：

PHYSICAL REVIEW LETTERS | 1995年 / 75卷 / 17期

关键词：

D O I：

10.1103/PhysRevLett.75.3154

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Neutron diffraction patterns of dotriacontane (n-C32D66) monolayers adsorbed on an exfoliated graphite substrate from a heptane (n-C7D16) solution reveal striking differences in the molecular orientation, lattice constant, and coherence length from those of the same monolayer adsorbed from the gas phase. Neither n-C32D66 monolayer phase appears to be fully consistent with Groszek's model of n-alkane registry on the graphite (0001) surface. A reversible transformation between the two monolayer phases can be induced by adding as little as a monolayer of the heptane solvent.

引用

页码：3154 / 3157

页数：4

共 19 条

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