DEPENDENCE OF MEMBRANE-POTENTIAL ON PH IN PERFLUOROCARBOXYLATE MEMBRANE AQUEOUS ALKALI-METAL CHLORIDE SYSTEMS

被引：1

作者：

NOMURA, K

YAMANOKUCHI, K

机构：

[1] Chemistry Laboratory, College of General Education, Kyushu University 01, Chuo-ku, Fukuoka, 810, Ropponmatsu

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1993年 / 352卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(93)80257-I

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Using a perfluorocarboxylate membrane as a cation exchange membrane, we investigated the effects of pH on the membrane potential in aqueous alkali metal chloride solutions and evaluated the permselectivities of the alkali metal ions and the hydrogen ion. The pH dependence of the membrane potential showed a biphasic behavior. The experimental results obeyed different theoretical curves in the high and low pH regions, so that two permselectivity coefficients were obtained for the alkali metal ions. The selectivities follow the order H+ > K+ > Na+ > Li+.

引用

页码：99 / 106

页数：8

共 29 条

[1] MATERIAL PROPERTIES OF CATION-EXCHANGE MEMBRANES FOR CHLOR-ALKALI ELECTROLYSIS, WATER ELECTROLYSIS AND FUEL-CELLS
ASAWA, T
[J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1989, 19 (04) : 566 - 570
[2] NON-STEADY STATE MEMBRANE POTENTIAL OF ION EXCHANGERS WITH FIXED SITES
CONTI, F
EISENMAN, G
[J]. BIOPHYSICAL JOURNAL, 1965, 5 (02) : 247 - &
[3] CONWAY BE, 1981, IONIC HYDRATION CHEM, P725
[4] Eisenberg A., 1970, MACROMOLECULES, V3, P147
[5] AC IMPEDANCE INVESTIGATION OF THE KINETICS OF ION-TRANSPORT IN NAFION PERFLUOROSULFONIC MEMBRANES
GAVACH, C
PAMBOUTZOGLOU, G
NEDYALKOV, M
POURCELLY, G
[J]. JOURNAL OF MEMBRANE SCIENCE, 1989, 45 (1-2) : 37 - 53
[6] ION-TRANSPORT AND CLUSTERING IN NAFION PERFLUORINATED MEMBRANES
HSU, WY
GIERKE, TD
[J]. JOURNAL OF MEMBRANE SCIENCE, 1983, 13 (03) : 307 - 326
[7] ION TRANSPORT THROUGH CELL MEMBRANE
KIMIZUKA, H
KOKETSU, K
[J]. JOURNAL OF THEORETICAL BIOLOGY, 1964, 6 (02) : 290 - &
[8] TRANSPORT OF ELECTROLYTES ACROSS CHARGED MEMBRANES .4. FRICTIONAL INTERACTIONS OF THE NEUTRAL AND ALKALINE PERMEANTS AND THE PERMEABILITY REFLECTION PHENOMENA
KUJAWSKI, W
NAREBSKA, A
[J]. JOURNAL OF MEMBRANE SCIENCE, 1991, 56 (01) : 99 - 112
[9] LAKSHMINARAYANA.N, 1969, TRANSPORT PHENOMENA, P58
[10] A STUDY OF THE SUPERSELECTIVITY OF NAFION PERFLUOROSULFONIC MEMBRANES
LINDHEIMER, A
MOLENAT, J
GAVACH, C
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 216 (1-2): : 71 - 88

← 1 2 3 →