COPOLYMERIZATION OF ETHYLENE CARBON-MONOXIDE BY A CATIONIC HYDRIDOAQUOPALLADIUM COMPLEX

被引：18

作者：

VALLI, VLK ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1995年 / 33卷 / 10期

关键词：

CARBONYLATION; 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE; COPOLYMERIZATION;

D O I：

10.1002/pola.1995.080331018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The cationic hydridoaquopalladium(II) complex, trans-[(PCy(3))(2)Pd(H)(H2O)](BF4-)-B-+, is an excellent catalyst for the ethylene/carbon monoxide alternating copolymerization in the presence of a bidentate phosphorus ligand and p-toluenesulphonic acid. (C) 1995 John Wiley and Sons, Inc.

引用

页码：1715 / 1718

页数：4

共 16 条

[1] HEMILABILE P,O-LIGANDS IN PALLADIUM-CATALYZED C-C LINKAGES - CODIMERIZATION OF ETHYLENE AND STYRENE AND COOLIGOMERIZATION OF ETHYLENE AND CARBON-MONOXIDE [J].