CO-2(CO)(8)-CATALYZED REACTION OF AROMATIC-ALDEHYDES WITH HYDROSILANES UNDER CARBON-MONOXIDE AS 1 ATM - INCORPORATION OF CO INTO THE CARBONYL CARBON-ATOM OF ALDEHYDES

被引：9

作者：

CHATANI, N ^{[1
]}

TOKUHISA, H ^{[1
]}

KOKUBU, I ^{[1
]}

FUJII, S ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 499卷 / 1-2期

关键词：

COBALT; SILICON; HYDROSILANE; ALDEHYDE; CARBON MONOXIDE; OXYMETHYLATION;

D O I：

10.1016/0022-328X(95)00303-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Co-2(CO)(8)-catalyzed reaction of aromatic aldehydes with hydrosilanes under CO as 1 atm results in incorporation of CO into the carbonyl carbon atom of aldehydes to give arylethane-1,2-diol disilyl ethers as the main product. The reaction of aliphatic aldehydes gives similar products, only with low yields.

引用

收藏

页码：193 / 197

页数：5

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